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Kramers-Kronig relations

In mathematics and physics, the Kramers-Kronig relations describe the relation between the real and imaginary part of a certain class of complex-valued functions. The requirements for a function f(ω) to which they apply can be interpreted as that the function must represent the Fourier transform of a linear and causal physical process. If we write

f(ω) = f1(ω) + if2(ω),

where f1 and f2 are real-valued "well-behaving" functions, then the Kramers-Kronig relations are

f_1(\omega) = \frac{2}{\pi} \int_0^{\infty}  \frac{\omega' f_2(\omega') d\omega'}{\omega^2 - \omega'^2}
f_2(\omega) = -\frac{2 \omega}{\pi} \int_0^{\infty}  \frac{f_1(\omega') d\omega'}{\omega^2 - \omega'^2}.

The Kramers-Kronig relations are related to the Hilbert transform, and are most often applied on the permittivity ε(ω) of materials. However, it must be noticed that in this case,

f(ω) = χ(ω) = ε(ω) / ε0 - 1,

where χ(ω) is the electric susceptibility of the material. The susceptibility can be interpreted as the Fourier transform of the time-dependent polarization in the material after an infinitely short pulsed electric field, in other words the impulse response of the polarization.

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